diff --git a/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/controller/TestRecordReagentController.java b/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/controller/TestRecordReagentController.java
index 2e564d9..d82b546 100644
--- a/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/controller/TestRecordReagentController.java
+++ b/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/controller/TestRecordReagentController.java
@@ -44,11 +44,15 @@ public class TestRecordReagentController {
     @PutMapping("/updateReagent")
     @ApiOperation(value = "修改实验使用试剂耗材、标准物质", notes = "")
     public R updateReagent(@RequestBody TestRecordReagent testRecordReagent) {
-        TestRecordReagent ret = testRecordReagentService.updateTestRecordReagent(testRecordReagent);
-        if (ret != null) {
-            return R.ok(ret, "添加成功");
-        } else {
-            return R.failed("false", "添加失败");
+        try {
+            TestRecordReagent ret = testRecordReagentService.updateTestRecordReagent(testRecordReagent);
+            if (ret != null) {
+                return R.ok(ret, "添加成功");
+            } else {
+                return R.failed("false", "添加失败");
+            }
+        } catch (Exception e) {
+            return R.failed(e.getMessage());
         }
     }
 
diff --git a/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/entity/TestRecordSampleDataExpand.java b/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/entity/TestRecordSampleDataExpand.java
index 6a63bb9..a8367ab 100644
--- a/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/entity/TestRecordSampleDataExpand.java
+++ b/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/entity/TestRecordSampleDataExpand.java
@@ -55,4 +55,13 @@ public class TestRecordSampleDataExpand extends BaseEntity {
      */
     private BigDecimal fragmentRetTime;
 
+    /**
+     * 质荷比(m/z)， nps案件
+     */
+    private BigDecimal massToChargeRatio;
+
+    /**
+     * 定性离子对，生物案件使用
+     */
+    private String qualitativeIonPair;
 }
diff --git a/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordReagentServiceImpl.java b/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordReagentServiceImpl.java
index 95e1c2d..e08cab9 100644
--- a/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordReagentServiceImpl.java
+++ b/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordReagentServiceImpl.java
@@ -7,6 +7,7 @@ import com.baomidou.mybatisplus.core.toolkit.Wrappers;
 import com.baomidou.mybatisplus.extension.plugins.pagination.Page;
 import com.baomidou.mybatisplus.extension.service.impl.ServiceImpl;
 import digital.laboratory.platform.common.aop.annotation.DlpResultProc;
+import digital.laboratory.platform.common.core.exception.CheckedException;
 import digital.laboratory.platform.inspection.convert.TestRecordReagentConvert;
 import digital.laboratory.platform.inspection.dto.TestRecordArgumentDto;
 import digital.laboratory.platform.inspection.entity.TestRecordReagent;
@@ -76,10 +77,10 @@ public class TestRecordReagentServiceImpl extends ServiceImpl<TestRecordReagentM
 
     @Override
     public TestRecordReagent updateTestRecordReagent(TestRecordReagent testRecordReagent) {
-        if (testRecordReagent.getSource() == 0) {
-            log.info("数据是其他系统推送录入的，不能修改");
-            return null;
-        }
+//        todo 添加了标准品成分，必填，其他系统过来的可以修改
+//        if (testRecordReagent.getSource() == 0) {
+//            throw new CheckedException("数据是其他系统推送录入的，不能修改");
+//        }
         boolean ret = this.updateById(testRecordReagent);
         if (ret) {
             return testRecordReagent;
@@ -123,7 +124,8 @@ public class TestRecordReagentServiceImpl extends ServiceImpl<TestRecordReagentM
      * @return
      */
     @Override
-    public IPage getTestRecordReagentPageList(Page page, String testId, String keywords, String category, Integer opCode) {
+    @DlpResultProc
+    public IPage<TestRecordReagentVO> getTestRecordReagentPageList(Page page, String testId, String keywords, String category, Integer opCode) {
         List<String> categoryList = getCategoryList(category);
         TestRecordVo testRecordVo = testRecordMapper.getTestRecordMapById(testId);
         return testRecordReagentPage(page, keywords, opCode, categoryList, testRecordVo.getReagentConsumablesList());
@@ -140,7 +142,8 @@ public class TestRecordReagentServiceImpl extends ServiceImpl<TestRecordReagentM
      * @return
      */
     @Override
-    public IPage getTestTemplateReagentPageList(Page page, String templateId, String keywords, String category, Integer opCode) {
+    @DlpResultProc
+    public IPage<TestRecordReagentVO> getTestTemplateReagentPageList(Page page, String templateId, String keywords, String category, Integer opCode) {
         List<String> categoryList = getCategoryList(category);
         TestTemplateVo templateVo = testTemplateMapper.getTestTemplateMapById(templateId);
         return testRecordReagentPage(page, keywords, opCode, categoryList, templateVo.getReagentConsumables());
@@ -156,7 +159,6 @@ public class TestRecordReagentServiceImpl extends ServiceImpl<TestRecordReagentM
      * @param reagentConsumablesList 试剂耗材ID列表，用于筛选符合条件的记录
      * @return 分页结果
      */
-    @DlpResultProc
     public IPage<TestRecordReagentVO> testRecordReagentPage(Page page, String keywords, Integer opCode, List<String> categoryList, List<String> reagentConsumablesList) {
         LambdaQueryWrapper<TestRecordReagent> queryWrapper = new LambdaQueryWrapper<>();
         queryWrapper.and(StringUtils.isNotBlank(keywords), qw -> qw
diff --git a/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordSampleDataServiceImpl.java b/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordSampleDataServiceImpl.java
index 4ce8682..c57888e 100644
--- a/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordSampleDataServiceImpl.java
+++ b/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordSampleDataServiceImpl.java
@@ -1861,9 +1861,7 @@ public class TestRecordSampleDataServiceImpl extends ServiceImpl<TestRecordSampl
                 .eq(TestRecordSampleData::getTestId, data.getTestId())
                 .eq(TestRecordSampleData::getSampleType, "STD"));
 
-        if (
-                data.getTargetRtTime() != null && std.getTargetRtTime() != null
-        ) {
+        if ( data.getTargetRtTime() != null && std.getTargetRtTime() != null ) {
             TestRecord testRecord = testRecordService.getById(data.getTestId());
             if (testRecord.getBusinessType().equals(BusinessType.BOINT_CASE.getBusinessType())) {
                 data.setRtTimeWithinError(
diff --git a/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordSampledataExpandServiceImpl.java b/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordSampledataExpandServiceImpl.java
index 7a000af..7fb539e 100644
--- a/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordSampledataExpandServiceImpl.java
+++ b/dlp-drugtesting-biz/src/main/java/digital/laboratory/platform/inspection/service/impl/TestRecordSampledataExpandServiceImpl.java
@@ -1,5 +1,6 @@
 package digital.laboratory.platform.inspection.service.impl;
 
+import cn.hutool.core.util.StrUtil;
 import com.baomidou.mybatisplus.core.toolkit.IdWorker;
 import com.baomidou.mybatisplus.extension.service.impl.ServiceImpl;
 import digital.laboratory.platform.inspection.constant.TestRecordSampleDataConstant;
@@ -38,13 +39,13 @@ public class TestRecordSampledataExpandServiceImpl extends ServiceImpl<TestRecor
         // 设置基峰的扩展数据
         if (!TestRecordSampleDataConstant.isInvalidValue(hairSewageDataDto.getPeakAreaUp())) {
             hairSewageInspectExpDataList.add(createTestRecordSampleDataExpand(testDataId, Boolean.TRUE,
-                    hairSewageDataDto.getPeakAreaUp(), null, null, null, null));
+                    hairSewageDataDto.getPeakAreaUp(), null, null, null, null, null, hairSewageDataDto.getQualitativeIonPairUp(), null));
         }
 
         if (!TestRecordSampleDataConstant.isInvalidValue(hairSewageDataDto.getPeakAreaDown())) {
             hairSewageInspectExpDataList.add(createTestRecordSampleDataExpand(testDataId, Boolean.FALSE,
                     hairSewageDataDto.getPeakAreaDown(), hairSewageDataDto.getIonAbundanceRatio(),
-                    hairSewageDataDto.getIonAbundanceRatioWithinError(), hairSewageDataDto.getWhetherCheckOut(), null));
+                    hairSewageDataDto.getIonAbundanceRatioWithinError(), hairSewageDataDto.getWhetherCheckOut(), null, null, hairSewageDataDto.getQualitativeIonPairDown(), null));
         }
 
         return hairSewageInspectExpDataList;
@@ -70,7 +71,9 @@ public class TestRecordSampledataExpandServiceImpl extends ServiceImpl<TestRecor
                     item.getAbundanceRatio(),
                     item.getAbundanceRatioError(),
                     item.getWithinError(),
-                    null
+                    item.getRetTime(),
+                    item.getMass(),
+                    null, null
             );
         }).collect(Collectors.toList());
 
@@ -81,13 +84,16 @@ public class TestRecordSampledataExpandServiceImpl extends ServiceImpl<TestRecor
     /**
      * 根据提供的参数创建一个TestRecordSampleDataExpand对象。
      *
-     * @param testDataId 测试数据ID
-     * @param isBasePeak 是否为基本峰
-     * @param peakArea 峰面积
-     * @param ionAbundanceRatio 离子丰度比
-     * @param ionAbundanceRatioError 离子丰度比误差
+     * @param testDataId                   测试数据ID
+     * @param isBasePeak                   是否为基本峰
+     * @param peakArea                     峰面积
+     * @param ionAbundanceRatio            离子丰度比
+     * @param ionAbundanceRatioError       离子丰度比误差
      * @param ionAbundanceRatioWithinError 离子丰度比是否在误差范围内
-     * @param someOtherValue 其他值
+     * @param retTime                      碎片保留时间，目前该字段仅对nps实验有用
+     * @param mass                         质荷比(m/z)，nps案件
+     * @param qualitativeIonPair           定性离子对，生物案件使用
+     * @param someOtherValue               其他值
      * @return 创建的TestRecordSampleDataExpand对象
      */
     private TestRecordSampleDataExpand createTestRecordSampleDataExpand(
@@ -97,6 +103,9 @@ public class TestRecordSampledataExpandServiceImpl extends ServiceImpl<TestRecor
             Double ionAbundanceRatio,
             Double ionAbundanceRatioError,
             String ionAbundanceRatioWithinError,
+            Double retTime,
+            String mass,
+            String qualitativeIonPair,
             Double someOtherValue
     ) {
         TestRecordSampleDataExpand testRecordSampleDataExpand = new TestRecordSampleDataExpand();
@@ -117,6 +126,14 @@ public class TestRecordSampledataExpandServiceImpl extends ServiceImpl<TestRecor
             testRecordSampleDataExpand.setIonAbundanceRatioWithinError(ionAbundanceRatioWithinError);
         }
 
+        if (retTime != null) {
+            testRecordSampleDataExpand.setFragmentRetTime(BigDecimal.valueOf(retTime));
+        }
+
+        if (StrUtil.isNotBlank(mass)) {
+            testRecordSampleDataExpand.setMassToChargeRatio(new BigDecimal(mass));
+        }
+
         // 如果有其他需要设置的值，可以继续扩展
         if (someOtherValue != null) {
             // 处理其他值的设置逻辑
diff --git a/dlp-drugtesting-biz/src/main/resources/mapper/TestRecordSampleDataExpandMapper.xml b/dlp-drugtesting-biz/src/main/resources/mapper/TestRecordSampleDataExpandMapper.xml
index c54359d..b64b95c 100644
--- a/dlp-drugtesting-biz/src/main/resources/mapper/TestRecordSampleDataExpandMapper.xml
+++ b/dlp-drugtesting-biz/src/main/resources/mapper/TestRecordSampleDataExpandMapper.xml
@@ -13,6 +13,8 @@
             <result property="ionAbundanceRatioError" column="ion_abundance_ratio_error" jdbcType="DECIMAL"/>
             <result property="ionAbundanceRatioWithinError" column="ion_abundance_ratio_within_error" jdbcType="VARCHAR"/>
             <result property="fragmentRetTime" column="fragment_ret_time" jdbcType="DECIMAL"/>
+            <result property="massToChargeRatio" column="mass_to_charge_ratio" jdbcType="DECIMAL"/>
+            <result property="qualitativeIonPair" column="qualitative_ion_pair" jdbcType="VARCHAR"/>
             <result property="createBy" column="create_by" jdbcType="VARCHAR"/>
             <result property="createTime" column="create_time" jdbcType="TIMESTAMP"/>
             <result property="updateBy" column="update_by" jdbcType="VARCHAR"/>
@@ -28,6 +30,8 @@
             exp.ion_abundance_ratio_error,
             exp.fragment_ret_time
             exp.ion_abundance_ratio_within_error,
+            exp.mass_to_charge_ratio,
+            exp.qualitative_ion_pair,
             exp.create_by,
             exp.create_time,
             exp.update_by,